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Juventus, who hold Juventus, collapsed Wednesday at Atalanta in a 3-0 defeat at Atalanta. Striker Duvan Zapata scored two goals to retain his electric form.
Timothy Castagne and Zapata struck in the 37th and 39th minutes to surprise the winning record 13 times, while Colombian striker Zapata scored an extra goal to stage a semifinal matchup with Fiorentina.
Atalanta, who drew 2-2 against Juventus, Serie A leader in Bergamo in December, had another surprise result, ensuring that Juve would not win the competition for a fifth consecutive season.
Castagne caught up with Joao Cancelo and broke through the edge of the area to give the hosts the advantage, while Zapata took it off the second minute later.
Furious Juventus coach Mbadimiliano Allegri was sent off after throwing his jacket on the pitch after second goal. The old lady was not mobilized and did not manage to record a single shot in the first half.
Zapata earned his second goal in the finals, bringing his total to 17 goals in his last 10 games in all competitions.
Also on Wednesday, Federico Chiesa scored a hat-trick as Fiorentina humbled Rome 7-1 to reach the semifinals of Coppa Italia.
The 21-year-old Italian striker hit the post early in the match and scored twice in the first 18 minutes in Florence.
Aleksandar Kolarov scored for Roma before Luis Muriel went 3-1 at halftime.
Chiesa completed his hat trick in the second half, Giovanni Simeone had two and Marco Benbadi also found the net.
Edin Dzeko, Substitute, was expelled late for the visitors after arguing with the referee.
Only for the sixth time in the club's history has Rome conceded seven goals. Last time it was against Bayern Munich in 2014.
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