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Borussia Dortmund, Atletico Madrid, Schalke and Porto all got their ticket to the Champions League last Wednesday.
Dortmund earned their presence in the round of 16 with a 0-0 draw at home against Club Brugge.
Atletico has secured a spot in the playoffs by beating Monaco 2-0 thanks to the efforts of Antoine Griezmann and Koke in the first period in Madrid on Wednesday.
Porto and Schalke have pbaded Group D before the Portuguese beat their German visitors 3-1 while Galatasary bowed 2-0 against Lokomotiv Moscow earlier in Russia.
Barcelona took the lead in Group B with a 2-1 win over a resistant PSV Eindhoven while Lionel Messi scored and created a goal for Gerard Pique in the Netherlands.
On Tuesday, defending champions Real Madrid, Manchester City, Bayern Munich and Juventus qualified.
Manchester United, Roma and Ajax have also gone through.
In the sixth round, played on December 10 in the week of the match, Tottenham Hotspur must compete with the result of Inter Milan to rank second in Group B, but will face the undefeated club of Barcelona and host the PSV Eindhoven to San Siro.
In Group C, three clubs in Naples, Paris Saint-Germain and Liverpool can still qualify.
Last year's finalists had to beat the Italians 1-0 or by two clear goals to Anfield and all that PSG had to do was claim a point to Belgrade's red star.
Shakhtar Donetsk and Lyon face each other in front of Kharkiv but Ukrainians have to beat visitors for last place in Group F.
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